On the artificial structure of the water dimer in the CNDO/2 method
✍ Scribed by Józef Lipiński
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 110 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
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The infrared spectrum of the mixed water dime1 HtO.DzO has been obscrvcd at 20 K in a nitrogen matri>r. The O-H(D) . . . 0 stretchins vibrations rut found to be slightly shifted compared to the ccrresponding vibrations in (HzO)? and (DzO)z, The results are intcrprctcd as evidence for the open dimer
Molecular-beam depletion spectroscopy has been employed to study the dissociation of mixed methanol-water clusters upon excitation of the C-O stretch vibration of the methanol constituent at 9.7 urn. Using the scattering selection technique, we were able to measure a methanol-water dimer dissociatio