Molecular-beam depletion spectroscopy has been employed to study the dissociation of mixed methanol-water clusters upon excitation of the C-O stretch vibration of the methanol constituent at 9.7 urn. Using the scattering selection technique, we were able to measure a methanol-water dimer dissociatio
On the structure of the water dimer
✍ Scribed by Leif Fredin; Bengt Nelander; Göran Ribbeg»rd
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 136 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The infrared spectrum of the mixed water dime1 HtO.DzO has been obscrvcd at 20 K in a nitrogen matri>r. The O-H(D) . . . 0 stretchins vibrations rut found to be slightly shifted compared to the ccrresponding vibrations in (HzO)? and (DzO)z, The results are intcrprctcd as evidence for the open dimer structure of Tursi 2nd Nixon.
📜 SIMILAR VOLUMES
The He.1 phoroclrcrron spectrum oithe gas-phase water dimcr produced III ZI supersonic nozzle beam was mcssurcd bclow 13.5 cV.Thc lirst and second vcrtlcti lonlzxtlon energes are 11.1 L 0 1 .md 13.2 ! 0 2 cV. These 180 lomc SI~ICS are mtcrprcwd III terms of ab IIU~IO calculauons