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On the affinities of ammonia and water for Li+, Na+ and K+

✍ Scribed by H. Berthod; A. Pullman

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
351 KB
Volume
70
Category
Article
ISSN
0009-2614

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✦ Synopsis

The affmlbes of ammoma for Na+and K+, recently determined experunentally, have been computed by the ab uutlo SW method usmg extended polarized gauwan basis sets and shown to be satlsfactory Furthermore, the correspondmg values computed at the same level of accuracy for the three catrons LI+, Na+, K+and the two hgands NH3 and Hz0 are shown to yield the order LI+> Na+> KC for each hgand and NH3 > Hz0 for each Ion, in agreement wth evpenment An anal)s~s of the Isctors mvolved m the bmdlng provides a comastent ratlonahzatlon of these regulantles and of some observed correlations I. Introduction An mcreasmg amount of InformatIon on the gas-

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