## Abstract Experimental investigations on the cosurfactant effect of alkali and tetraalkylammonium choleates in water/AOT/cyclohexane (W/O)‐microemulsions were carried out. The results prompted considerations on a thermodynamic and molecular level. The molecular view emphasizes the significance of
On the Activity of Water and the Concept of the Interfacial Free Energy in W/O-Microemulsions
✍ Scribed by Rudolf Kubik; Hans-Friedrich Eicke; Bengt Jönsson
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- German
- Weight
- 448 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The water activity and its temperature dependence as a function of the amount of water in the L~2~‐phase of the (water/Aerosol OT/isooctane)‐system (s. Exper. Part) was determined with the help of a differential pressure gauge and a precision cathetometer. A theoretical approach based essentially upon a solution of the Poisson‐Boltzmann equation with appropriate boundary conditions led to a description of the activity plot in excellent agreement with experimental results.
📜 SIMILAR VOLUMES
## Abstract Solutions of blockcopolymers (POE‐b‐PI‐b‐POE) in fluids of interacting aqueous nanodroplets (W/O microemulsions) are studied. The interaction strength between the (pseudo) two components is measured by the shift of the percolation temperature relative to that of the pure microemulsion.
percolation'' and justify the mechanism behind it but a defi-Both water-induced and temperature-induced percolation of nite conclusion in this regard is still awaited. We have recently water/AOT/heptane water-in-oil microemulsion have been studstudied (19) the effects of various additives on the pro
additives on the size (4-6), on electrical percolation pro-Using steady state and time resolved fluorescence techniques, cesses (7-9), or on the formation of microemulsion gels the photophysical parameters of acridone in w/o microemulsions (10)(11)(12). of aerosol OT/isooctane were obtained. The re
The surface area occupied at the air/water interface for cycloalkanols and ␣,-alkanediols has been estimated from surface tension measurements. From these data, standard free energies of transfer of the alkanols from the bulk of the solution to the interface were obtained. Cycloalkanols constitute a
We carried out an investigation on the influence of several alkylamines, frequently present in reactions carried out in microemulsions, on the properties of the water/AOT/isooctane system. The presence of alkylamines has an important effect on the electrical percolation phenomena. This effect of ami