On skewed ARC plots of impedance of electrodes with an irreversible electrode process

✍ Scribed by Amos Maritan; Flavio Toigo

• Book ID: 103064803
• Publisher: Elsevier Science
• Year: 1990
• Tongue: English
• Weight: 401 KB
• Volume: 35
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/0013-4686(90)85051-n

✦ Synopsis

By

a careful analysis of the form of the current lmphed by the boundary condltlons satisfied by the solution of Poisson's equation, we generahze previous results and show that lrreverslble redox processes at a self slmllarly rough (fractal) electrode gve rise to a skewed arc plot m the complex Impedance-plane We also discuss the form of scaling relations obeyed by the current at the electrode to ensure the vahdlty of Ohm's law m the solutton