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On-line capillary supercritical fluid chromatography-inductively coupled plasma mass spectrometry for the analysis of organometallic compounds

✍ Scribed by Blake, Earl ;Raynor, Mark W. ;Cornell, David

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
507 KB
Volume
18
Category
Article
ISSN
0935-6304

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✦ Synopsis

Supercritical fluid chromatography with inductively coupled plasma-mass spectrometric detection is a new and useful technique

for the analysis of organometallic compounds. An interface has been developed for coupling these techniques. The interface is compact, easy to assemble, and causes minimal disruption to either instrument. A series of organotin, organoarsenic, and organoiron compounds has been used to evaluate the interface and ICPMS as a detector for SFC. The effect of analyte concentration and restrictor temperature on peak intensity has been investigated and the effect of the mobile phase on the plasma has also been studied to assess background interference from changes in the plasma.

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