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On features of the conformational ordering of natural and synthetic cis-1,4-polyisoprenes

✍ Scribed by K.V Nel'son; A.P Berezkina; S.K Kurlyand

Book ID: 116047612
Publisher: Elsevier Science
Year: 1985
Weight: 526 KB
Volume: 27
Category: Article
ISSN: 0032-3950
DOI: 10.1016/0032-3950(85)90359-4

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## Abstract In the presence of chlorinated solvents, the catalytic complex [Ir(COD)py(PCy~3~)]PF~6~ (where COD is 1,5‐cyclooctadiene and py is pyridine) was an active catalyst for the hydrogenation of synthetic __cis__‐1,4‐polyisoprene and natural rubber. Detailed kinetic and mechanistic studies fo