𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On electron attachment to HBO2: A comment

✍ Scribed by William J. Miller; Robert K. Gould

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
70 KB
Volume
49
Category
Article
ISSN
0009-2614

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✦ Synopsis

It has becn pointed out that the attachment reaction (\mathrm{e}+\mathrm{HBO}{2} \rightarrow \mathrm{BO}{2}^{-}+\mathrm{H}) is close to or at equilibrium throughout large regions of the high temperature test flames in which its rate coefficient was determined. This is indeed the case but only in the later stages of the flames; the rate constant is derived from species concentration measurements in the early parts of the fiames prior to the attainment of equilibrium.

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The pressure dependence of electron attachment to 0, has been measured, at 296" C, using relaxation and steady state microwave conductivity methods. fi'hen the r&&s from the former method ;LI~ corrected for the natural time response of the apparatus good agreement between the two methods is found an