## Synthesis of the Propyl Glycosides of the TrisaccharideP-D-Galp-(l+3)-P-D-GalpNAc-(1+3)-a-D-Galp and of the Tetrasaccharide E-L-Fuc~-(~+~)-/?-D-Galp-(1+3)-j?-~-GalpNAc-(1+3)-a-D-Galp, Components of a Tumor Antigen ') part 2: [I].
✦ LIBER ✦
Oligosaccharides Related to Tumor-Associate Antigens. Part 2. Conformational analysis of the trisaccharide α-L-Fucp-(1→2)-β-D-Galp-(1→3)-β-D-GalpNAc, epitope structure recognized by the MBr1 antibody
✍ Scribed by Lucio Toma; Pierangela Ciuffreda; Diego Colombo; Fiamma Ronchetti; Luigi Lay; Luigi Panza
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- German
- Weight
- 570 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0018-019X
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The synthesis of the trisaccharide c ! -L-Fuc~-( 1 +2)-p-o-Ga1pp-( 1 +3)-P-~-GalpNAc-l-OPr (2) is described. The N-acetylgalactosamine 6 was obtained from 4 by an intramolecular displacement of a (trifluo-romethy1)sulfonyloxy by a pivaloyloxy group with its concomitant migration from position 3 to p