Oligosaccharide Synthesis Based on Glycosyl Donors and Acceptors Carrying Phosphorus-Containing Leaving Groups. -By employing the tetramethylphosphoramidate group as an anomeric protecting group as well as a leaving group, an efficient strategy for the synthesis of oligosaccharides is reported.
Oligosaccharide synthesis based on glycosyl donors and acceptors carrying phosphorus-containing leaving groups
β Scribed by Shun-ichi Hashimoto; Hiroki Sakamoto; Takeshi Honda; Shiro Ikegami
- Book ID
- 104257478
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 285 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
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π SIMILAR VOLUMES
A convergent synthesis of ganglioside GM 3 has been achieved by capitalizing on three different phosphorus-containing leaving groups, in which the key features involve a chemo-and regioselective a-glycosidation of sialyl phosphite with partially benzylated galactosyl tetramethylphosphorodiamidate by