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Oligosaccharide synthesis based on glycosyl donors and acceptors carrying phosphorus-containing leaving groups

✍ Scribed by Shun-ichi Hashimoto; Hiroki Sakamoto; Takeshi Honda; Shiro Ikegami


Book ID
104257478
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
285 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


Efficient OnttketiΒ’ strate~ for oltso~ccharid~ has been developed by e~loitk~ 8 the ~ ~ a~sw~c _re~_..~o~ Z~wm SP~O~ demors a~t accep~ors carr~ low~m~~ leavk~g group& where~ the tetrametAyiplu~phoroemidate group plays a pivotal role as anomeric protecavegroup as we//as leavtqgroup.


πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Oligosaccharide Syn
✍ S. HASHIMOTO; H. SAKAMOTO; T. HONDA; S. IKEGAMI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 25 KB πŸ‘ 2 views

Oligosaccharide Synthesis Based on Glycosyl Donors and Acceptors Carrying Phosphorus-Containing Leaving Groups. -By employing the tetramethylphosphoramidate group as an anomeric protecting group as well as a leaving group, an efficient strategy for the synthesis of oligosaccharides is reported.

Chemoselective glycosidation strategy ba
✍ Hiroki Sakamoto; Seiichi Nakamura; Toshifumi Tsuda; Shunichi Hashimoto πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 117 KB

A convergent synthesis of ganglioside GM 3 has been achieved by capitalizing on three different phosphorus-containing leaving groups, in which the key features involve a chemo-and regioselective a-glycosidation of sialyl phosphite with partially benzylated galactosyl tetramethylphosphorodiamidate by