𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Olefin radical cations in pulse radiolysis of hydrocarbons.time-resolved fluorescence-detected magnetic resonance

✍ Scribed by D.W. Werst; M.F. Desrosiers; A.D. Trifunac

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
545 KB
Volume
133
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Olefin radical cations are characterized by time-resolved fluorescence-detected magnetic resonance (FDMR) in pulse radiolysis of saturated hydrocarbons. Studies of both neat and mixed saturated hydrocarbon fluids by FDMR at low temperatures (to = 100Β°C) suggest that olefin cations originate in the fragmentation of (vibrationally) excited (parent) saturated hydrocarbon cations.

πŸ“œ SIMILAR VOLUMES

Observation of transient cyclohexene and
Observation of transient cyclohexene and 1,4-cyclohexadiene radical cations. Time-resolved fluorescence-detected magnetic resonance
✍ M.F. Desrosiers; A.D. Trifunac πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 231 KB

Transient radical cations of cyclohcxcne and l+cyclohexadlene are characterized in pulse radiolysis in Equid hydrocarbons. Time-resolved tluorscenc+de~ected magnetic resonance allows observtion and EPR special assignment 01 These very short-lived radical cations. The olefii radical cations are creat

Optically detected time resolved epr of
Optically detected time resolved epr of radical ion pairs in pulse radiolysis of liquids
✍ Alexander D. Trifunac; Joseph P. Smith πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 371 KB

Tune resolved EPR spectra of aromatx radtcal ran paus are measured by optical detection of mtcrowave modulation (ODMR) of the fluorescence of ewtted aromattcs from recombtnatton of radtcal ton paus produced by pulse radlolysts ODMR data tn solutions of pyrcnc III dccahn mdlatc that gcmlnate recombma