Olefin radical cations are characterized by time-resolved fluorescence-detected magnetic resonance (FDMR) in pulse radiolysis of saturated hydrocarbons. Studies of both neat and mixed saturated hydrocarbon fluids by FDMR at low temperatures (to = 100Β°C) suggest that olefin cations originate in the f
β¦ LIBER β¦
Observation of transient cyclohexene and 1,4-cyclohexadiene radical cations. Time-resolved fluorescence-detected magnetic resonance
β Scribed by M.F. Desrosiers; A.D. Trifunac
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 231 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Transient radical cations of cyclohcxcne and l+cyclohexadlene are characterized in pulse radiolysis in Equid hydrocarbons. Time-resolved tluorscenc+de~ected magnetic resonance allows observtion and EPR special assignment 01 These very short-lived radical cations. The olefii radical cations are created by charge transfer from saturated hydrocarbon solvent cations
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