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Observation of transient cyclohexene and 1,4-cyclohexadiene radical cations. Time-resolved fluorescence-detected magnetic resonance

✍ Scribed by M.F. Desrosiers; A.D. Trifunac


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
231 KB
Volume
118
Category
Article
ISSN
0009-2614

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✦ Synopsis


Transient radical cations of cyclohcxcne and l+cyclohexadlene are characterized in pulse radiolysis in Equid hydrocarbons. Time-resolved tluorscenc+de~ected magnetic resonance allows observtion and EPR special assignment 01 These very short-lived radical cations. The olefii radical cations are created by charge transfer from saturated hydrocarbon solvent cations


πŸ“œ SIMILAR VOLUMES


Olefin radical cations in pulse radiolys
✍ D.W. Werst; M.F. Desrosiers; A.D. Trifunac πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 545 KB

Olefin radical cations are characterized by time-resolved fluorescence-detected magnetic resonance (FDMR) in pulse radiolysis of saturated hydrocarbons. Studies of both neat and mixed saturated hydrocarbon fluids by FDMR at low temperatures (to = 100Β°C) suggest that olefin cations originate in the f