✦ LIBER ✦

Olefin Metatheses in Metal Coordination Spheres: A New Approach to Steric Shielding in Dirhenium sp Carbon Chain Complexes of the Formula (η 5 -C 5 Me 5 )Re(NO)(PR 3 )(C⋮CC⋮CC⋮CC⋮C)(R 3 P)(ON)Re(η 5 -C 5 Me 5 )

✍ Scribed by Horn, Clemens R.; Martín-Alvarez, José Miguel; Gladysz, J. A.

Book ID: 127021222
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 169 KB
Volume: 21
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om020676y

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Syntheses of Dimetallamacrocycles by Int

Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear Bis(1,3-butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)dirhenium Complexes [(η5-C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)]

✍ Clemens R. Horn; John A. Gladysz 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

## Abstract Reactions of the chiral racemic carbonyl complex [(η^5^‐C~5~Me~5~)Re(NO)(NCCH~3~)(CO)]^+^·BF~4~^−^ and diphosphanes Ph~2~P(CH~2~)~__n__~PPh~2~ [2.4:1.0 mol ratio; __n__ = 10 (a), 14 (b)] give the (bridging phosphane)dirhenium complexes [(η^5^‐C~5~Me~5~)Re(NO)(CO){μ‐[PPh~2~(CH~2~)~__n__~

Cover Picture: Syntheses of Dimetallamac

Cover Picture: Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear Bis(1,3-butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)dirhenium Complexes [(η5-C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)] (Eur. J. Inorg. Chem. 12/2003)

✍ Clemens R. Horn; John A. Gladysz 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 74 KB 👁 1 views

Synthesis and reactivity of new heterodi

Synthesis and reactivity of new heterodinuclear iron/rhenium Cx complexes of the formula (η5-C5Me5)Re(NO)(PPh3)(CC)n(η2-dppe)Fe(η5-C5Me5) (n = 3, 4): Redox properties and a dicobalt hexacarbonyl adduct

✍ Slawomir Szafert; Frédéric Paul; Wayne E. Meyer; John A. Gladysz; Claude Lapinte 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 374 KB

Synthesis, Structure, and Reactivity of

Synthesis, Structure, and Reactivity of Polymetallic C 3 OMe Complexes of the Formula (η 5 -C 5 Me 5 )Re(NO)(PPh 3 )(C⋮CC(OMe))M m (CO) n (M/ m / n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in Which a C 3 Chain Links Two Metals and Spans a Third

✍ Falloon, Stephen B.; Weng, Weiqing; Arif, Atta M.; Gladysz, J. A. 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 243 KB

Attaching Metal-Capped sp Carbon Chains

Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries More Distorted than Planar Tetracoordinate

✍ Stephen B. Falloon; Slawomir Szafert; Atta M. Arif; J. A. Gladysz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 280 KB 👁 2 views

Reaction of [(h 5 -C 5 Me 5 )Re-(NO)(PPh 3 )(CCH)] (1) and [Os 3 -(CO) 10 (NCCH 3 ) 2 ] (CH 2 Cl 2 , room temperature) gives the ReC 2 Os 3 complex [(h 5 -C 5 Me 5 )Re(NO)(PPh 3 )(CC)Os 3 -(CO) 10 (H)] (2, 78 %). The crystal structure shows that the hydride and ReCC terminus bridge the same two osmi