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Olefin Epoxidation with a New Class of Ansa-Molybdenum Catalysts in Ionic Liquids

✍ Scribed by Daniel Betz; Alexander Raith; Mirza Cokoja; Fritz E. Kühn


Publisher
Wiley (John Wiley & Sons)
Year
2010
Tongue
English
Weight
261 KB
Volume
3
Category
Article
ISSN
1864-5631

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✍ Loubna Gharnati; Olaf Walter; Ulrich Arnold; Manfred Döring 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 434 KB

## Abstract Several penta‐ and hexaalkylated guanidinium‐based ionic liquids (GILs) were tested as solvents for the epoxidation of cyclooctene using the Venturello catalyst, [(C~8~H~17~)~3~N(CH~3~)]~3~[PO~4~{WO(O~2~)~2~}~4~], and hydrogen peroxide as the oxidant. Epoxide yields were obtained in a b