Olefin Cycloadditions of the Electrophilic Phosphinidene Complex [iPr2N−P=Fe(CO)4]
✍ Scribed by Jan B. M. Wit; Gerno T. van Eijkel; Franciscus J. J. de Kanter; Marius Schakel; Andreas W. Ehlers; Martin Lutz; Anthony L. Spek; Koop Lammertsma
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 125 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reactions of [N 3 P 3 (dobp) 2 Cl 2 ] and [N 3 P 3 (dobp)Cl 4 ] with revealed that the complexation of the N atom of one 4oxypyridine ligand by the W(CO) 5 fragment has a a mixture of HOC 5 H 4 N-4 and K 2 CO 3 in acetone give the cyclotriphosphazenes [N 3 P 3 (dobp) 2 (OC 5 H 4 N-4) 2 ] and [N
## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo