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Octa(phenylsilasesquioxane) acetone solvate

โœ Scribed by Hossain, M. A. ;Hursthouse, M. B. ;Malik, K. M. A.


Book ID
114526363
Publisher
International Union of Crystallography
Year
1979
Weight
311 KB
Volume
35
Category
Article
ISSN
0567-7408

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The title solvated salt, [Ir(H)~2~{P(C~6~H~11~)~3~}~2~{OC(CH~3~)~2~}~2~]BF~4~ยท(CH~3~)~2~CO, was obtained by the protonation of [Ir(H)~5~{P(C~6~H~11~)~3~}~2~] with HBF~4~ in acetone. The cation features __OC__-6-13 stereochemistry, with Irโ€”P = 2.3159โ€…(6) and 2.3267โ€…(6)โ€…ร…, and Irโ€”O = 2.238โ€…(1) and 2.2