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Octahedral Fe(II) and Ru(II) Complexes Based on a New Bis 1,10-Phenanthroline Ligand That Imposes a Well Defined Axis

✍ Scribed by Pomeranc, Didier; Heitz, Valérie; Chambron, Jean-Claude; Sauvage, Jean-Pierre


Book ID
111873372
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
126 KB
Volume
123
Category
Article
ISSN
0002-7863

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A bis 1,10-phenanthroline ligand leading
✍ Didier Pomeranc; Jean-Claude Chambron; Valérie Heitz; Jean-Pierre Sauvage 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 104 KB

A bis-chelating ligand (1), made of two 1,10-phenanthroline subunits connected with a p-(CH 2 ) 2 C 6 H 4 (CH 2 ) 2spacer through their 4 positions, has been prepared, using Skraup syntheses and reaction of the anion of 4-methyl-7anisyl-1,10-phenanthroline with α,α'-dibromo-p-xylene. Complexation of