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Octahedral cluster Mo complexes (Bz3NH)3[Mo6OCl13] and (Bz3NH)2[Mo6Cl14] · 2CH3CN: Synthesis, crystal structure and properties

✍ Scribed by Zh. S. Kozhomuratova; N. G. Naumov; D. Yu. Naumov; E. M. Uskov; V. E. Fedorov


Book ID
111458003
Publisher
SP MAIK Nauka/Interperiodica
Year
2007
Tongue
English
Weight
404 KB
Volume
33
Category
Article
ISSN
1070-3284

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✍ Zhyldyz S. Kozhomuratova; Yuri V. Mironov; Michael A. Shestopalov; Irina V. Dreb 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 218 KB

## Abstract New cluster compounds [H~3~O(Ph~3~PO)~3~]~2~[Mo~6~Cl~14~] (I) and [H(Ph~3~PO)~2~]~2~[Re~6~S~6~Br~8~] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph~3~PO with octahedral cluster complexes of molybdenum (H~3~O)~2~Mo~6~Cl~14~·6H~2~O and rh