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(OC-6-32)-Bis[5-bromo-2-(4-bromo­phenyl­diazen­yl)phen­yl]dicarbonyl­ruthenium(II)

✍ Scribed by Willis, Anthony C. ;Mahdi, Waleed K. ;Humphrey, Mark G.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
122 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Ru(C 12 H 7 Br 2 N 2 ) 2 (CO) 2 ], possesses a distorted octahedral environment about the Ru atom, with two cyclometallated 4,4 0 -dibromoazobenzene ligands and two mutually cis carbonyl ligands. The donor atoms are arranged such that the N atoms are respectively trans to a carbonyl ligand and an aryl C atom.

📜 SIMILAR VOLUMES

(OC-6-13)-Bis[5-bromo-2-(4-bromo­phenyl­
(OC-6-13)-Bis[5-bromo-2-(4-bromo­phenyl­diazenyl)phen­yl]dicarbonyl­ruthenium(II) with mutually transN-donor atoms
✍ Willis, Anthony C. ;Mahdi, Waleed K. ;Humphrey, Mark G. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 121 KB

The title compound, [Ru(C 12 H 7 Br 2 N 2 ) 2 (CO) 2 ], possesses a distorted octahedral environment about the Ru atom, with two cyclometallated 4,4 0 -dibromoazobenzene ligands and two mutually cis carbonyl ligands. The donor atoms are arranged such that the N atoms are mutually trans and the aryl

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Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.045 wR factor = 0.126 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

[μ-1,1′-Bis(2,4,6-trimethyl­benz­yl)-3,3
[μ-1,1′-Bis(2,4,6-trimethyl­benz­yl)-3,3′-(2,3,5,6-tetra­methyl-p-phenyl­enedibenzimidazole)-2,2′-diyl­idene]di-μ-bromo-disilver(I)
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0 -Bis(2,4,6-trimethylbenzyl)-3,3 0 0 0 -(2,3,5,6-tetramethyl-p-phenylenedibenzimidazole)-2,2 0 0 0 -diylidene]di-l-bromo-disilver(I) Bas ¸ak Kos ¸ar, a Hayati Tu ¨rkmen, b Bekir C ¸etinkaya b and Orhan Bu ¨yu ¨kgu ¨ngo ¨ra \*