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Observations on the Radiation Decomposition of Some C 14 -Labeled Compounds 1

✍ Scribed by Tolbert, B. M.; Adams, P. T.; Bennett, Edward L.; Hughes, Ann M.; Kirk, Martha R.; Lemmon, R. M.; Noller, R. M.; Ostwald, R.; Calvin, Melvin


Book ID
126072728
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
255 KB
Volume
75
Category
Article
ISSN
0002-7863

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Conditions were found for almost quantitative carboxylation of n-hexyllithium with l4CO2 to afford lithium [1-l4C] heptanoate. It was then possible to perform the reaction sequence lithium [1-l4C] heptanoate --+ [l-14C] heptan-1-01 + 1-bromo [l-14q heptane in one flask without isolation of intermed