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Observations on the Direct Amidocyclopropanation of Alkenes Using Organozinc Carbenoids.

✍ Scribed by William B. Motherwell; Guillaume Begis; David E. Cladingboel; Laure Jerome; Tom D. Sheppard

Book ID
102011242
Publisher
John Wiley and Sons
Year
2007
Weight
34 KB
Volume
38
Category
Article
ISSN
0931-7597

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The use of acetals and ketals as direct precursors for organozinc carbenoid chemistry is illustrated by their direct conversion to alkenes in a one pot operation. Aryl acetals can also be used as precursors for the cyclopropanation ofcyclohexene.