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ChemInform Abstract: Asymmetric Synthesis of Aminocyclopropanes and N-Cyclopropylamino Alcohols Through Direct Amidocyclopropanation of Alkenes Using Chiral Organozinc Carbenoids.

✍ Scribed by Guillaume Begis; David E. Cladingboel; Laure Jerome; William B. Motherwell; Tom D. Sheppard

Publisher
John Wiley and Sons
Year
2009
Weight
47 KB
Volume
40
Category
Article
ISSN
0931-7597

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Abstract

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Asymmetric Synthesis of Aminocyclopropan
Asymmetric Synthesis of Aminocyclopropanes and N-Cyclopropylamino Alcohols Through Direct Amidocyclopropanation of Alkenes Using Chiral Organozinc Carbenoids
✍ Guillaume Bégis; David E. Cladingboel; Laure Jerome; William B. Motherwell; Tom 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 464 KB

## Abstract Chiral __N__‐(diethoxymethyl)oxazolidinones, prepared from the corresponding oxazolidinones by heating in triethyl orthoformate, can be used as organozinc carbenoid precursors for the direct enantioselective amidocyclopropanation of alkenes. The reaction is successful with a wide range