ti general formula of the probability of vibrational transitions in diatomic molecules is formulated with specific consideration of vibration-vibration energy transfer for nonresonant cases. An application to HZ-H2 collisions shows an excellent agreement of the present formulation with exact quantum
Observations of Vibration–Vibration Energy Pumping between Diatomic Molecules
✍ Scribed by TEARE, J. D.; TAYLOR, R. L.; VON ROSENBERG, C. W.
- Book ID
- 109670743
- Publisher
- Nature Publishing Group
- Year
- 1970
- Tongue
- English
- Weight
- 445 KB
- Volume
- 225
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/225240a0
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A classical model for V-R and V-V energy transfer between two dissimilar diatomic molecules is proposed. For the exponential repulsive potentid, in the limit as the rotation of the mplecules goes to zero, the presenr model reduces to the previous resu!ts for V-T and V-V energy transfer. For the hydr
Vibrational zero-point energies ͑ZPEs͒, as determined from published spectroscopic constants, are derived for 85 diatomic molecules. Standard uncertainties are also provided, including estimated contributions from bias as well as the statistical uncertainties propagated from those reported in the sp