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Observations concerning the reactivity of bicyclomycin and bicyclomycin derivatives with organophosphorus reagents

✍ Scribed by Vela, Marco A.; Kohn, Harold

Book ID
127355536
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
562 KB
Volume
57
Category
Article
ISSN
0022-3263

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## Abstract The reaction of 1,3‐diphenyl‐2‐(phenylimino)‐3‐(ylidenemethyl‐acetate)‐1‐propanone **(5)** with trisdialkylaminophosphines **(6a,b)** in refluxing toluene afforded the new oxazaphospholene products **(7a–b)**. On the other hand, the cyclic azaphospholene adducts **8a–b** were isolated f