The dipole moment parameters \(\mu_{0}\) and \(\mu_{33}\) of \(\mathrm{SiF}_{4}\) have been determined previously from linear Stark effect observations on \(E\)-type transitions. These dipole moment parameters have been used to predict the nonlinear Stark effect which arises from interactions betwee
Observation of the Stark Effect in the ;gn3Band of Methane by Saturated Dispersion Technique
β Scribed by D.A. Tyurikov; E. Poernomo; G. Kramer
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 67 KB
- Volume
- 184
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
We report a theoretical and experimental investigation of the dynamical Stark effect in a tetrahedral molecule, silane (SiH(4)). We use a tetrahedral formalism and Floquet theory to calculate the absorption spectra for the molecule dressed by an intense nonresonant pulsed laser. Experimentally, the
The time-resolved optical Kerr effect was used to probe the ultrafast relaxation of four halogenated methanes, CHC&, CBrCl,, CHBr, and CFBr3. A 65 fs coherent laser pulse from a synchronously pumped antiresonant ring dye laser with Fourier components ranging over 300 cm-' is separated into a pump an
## Abstract The carbon kinetic isotope effect in the reaction of CH~4~ with OH has an experimentally measured value of 1.003. The measurement was performed using a static system in which the source of OH was the gasβphase photolysis of H~2~O~2~ with ultraviolet light produced by a highβpressure mer