𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Observation of the kramers turnover region in the isomerism of trans-stilbene in fluid ethane

✍ Scribed by Minyung Lee; G.R. Holtom; Robin M. Hochstrasser

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
447 KB
Volume
118
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

FlUOr csocnee of U-W-E-srilbcnc in erhane a~ 350 K gives tie ban-ie~ crossing rarcg a~ a funcrion of pressure in lhc range 0 IO 170 atm The dala dernonswatc a peak m the rate at I20 atm (a wlluion frequency of (6-7)x10" s-'. or a viscotity of 0.03 cP). The dam are diisscd in tof the dlmcnsionalily; clustering near Lhe crirical pressure; collisional deaclivalion: and

πŸ“œ SIMILAR VOLUMES

Dynamics of the isomerization of trans-s
Dynamics of the isomerization of trans-stilbene in n-alcohols studied by ultraviolet picosecond absorption recovery
✍ Villy SundstrΓΆm; Tomas Gillbro πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 559 KB

We have used a simple Ar+synchronously pumped and cavity-dumped dye-laser system to generate UV picosecond pulses with energies sufficiently high for absorption recovery experiments. With these pulses, we have studied the dynamics of the isomerization of trans-stilbene in n-alcohols as a function of

Exchange model of vibrational dephasing
Exchange model of vibrational dephasing in S1 trans-stilbene in solution and its possible correlation with the isomerization reaction
✍ Hiro-o Hamaguchi; Koichi Iwata πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 595 KB

The changes of the peak position and bandwidth of the oleftic C-C stretch Raman band of S, tram-stilbene in normal alkanes have been analyzed on the basis of an asymmetric exchange model in which the C-C stretch frequency hops to and fro between two discrete values belonging to two different electro