𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Observation of Bulk Susceptibility Effects in High-Resolution Nuclear Magnetic Resonance

✍ Scribed by Matthew P. Augustine; Kurt W. Zilm


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
318 KB
Volume
123
Category
Article
ISSN
1064-1858

No coin nor oath required. For personal study only.

✦ Synopsis


The phenomenon of multiple echoes following a two-pulse stimsulting from the nuclear dipolar demagnetizing field. This ulated-echo experiment in highly polarized systems is reinvestifield is proportional to a sample's magnetization and is negligated and explained using the Bloch equations. A semiquantitative gible when normal magnetic fields (õ12 T) and concentraformalism based on the nuclear contributions to the magnetic sustions (Ӷ55 M H 2 O) are used. It has long been understood ceptibility throughout a multiple-pulse sequence is outlined and that the back reaction of the dipolar demagnetizing field on used to understand the formation of the echoes. This theory is a sample's magnetization can lead to unexpected results. used to direct the design of phase-cycled and pulsed-field-gradient The production of multiple echoes by a stimulated echo experiments to control the echo formation. The theory also sug-(p/2-t-p/2) pulse sequence as first observed in solid gests a means of indirectly detecting a heteronucleus contained in 3 He is just one example. Deville and co-workers (4) demona different molecule. This kind of detection is accomplished by strated that these multiple echoes could be explained by modifying the static magnetic field with a stimulated-echo experiment on one set of the spins. Heteronuclear experiments show that adding terms to account for the dipolar demagnetizing contrithis classical semiquantitative formalism is a useful tool in the butions of the nuclear spins to the static field in the Bloch understanding of spin dynamics in highly polarized systems. equations. More recent work by Bowtell (5) showed that


📜 SIMILAR VOLUMES


High-resolution solid-state 195Pt nuclea
✍ Shigenobu Hayashi; Kikuko Hayamizu 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 354 KB

## Abstract High‐resolution solid‐state ^195^Pt NMR spectra of ammonium, potassium and sodium hexachloroplatinate(IV) and its hydrate were investigated using magic angle spinning of the sample. The isotropic part of the spectra has fine structure originating from dipole–dipole interaction and indir

High-resolution proton nuclear magnetic
✍ Erik A. Boss; Sytske H. Moolenaar; Leon F. A. G. Massuger; Henk Boonstra; Udo F. 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB 👁 2 views

Most ovarian tumors are cystic structures containing variable amounts of fluid. Several studies of ovarian cyst fluid focus on one specific metabolite using conventional assay systems. We examined the potential of 1 H-nuclear magnetic resonance spectroscopy in evaluation of the overall metabolic com

High-resolution 13C–nuclear magnetic res
✍ Maria Inês Bruno Tavares 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 65 KB 👁 1 views

## Abstract The combination of solid‐state nuclear magnetic resonance (NMR) techniques is very helpful for examining the behavior of heterogeneous amorphous polymers. With the magic‐angle spinning (MAS) technique, employing special conditions, only the mobile fraction of the molecule can be assigne