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High-resolution solid-state 195Pt nuclear magnetic resonance in hexachloroplatinates(IV)

✍ Scribed by Shigenobu Hayashi; Kikuko Hayamizu

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
354 KB
Volume
30
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

High‐resolution solid‐state ^195^Pt NMR spectra of ammonium, potassium and sodium hexachloroplatinate(IV) and its hydrate were investigated using magic angle spinning of the sample. The isotropic part of the spectra has fine structure originating from dipole–dipole interaction and indirect spin coupling between platinum and chlorine nuclei. The fine structure was analysed theoretically, yielding the indirect spin coupling constants and their anisotropies.

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