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Observation and interpretation of a time-delayed mechanism in the hydrogen exchange reaction

✍ Scribed by Althorpe, Stuart C.; Fernández-Alonso, Félix; Bean, Brian D.; Ayers, James D.; Pomerantz, Andrew E.; Zare, Richard N.; Wrede, Eckart

Book ID
109803087
Publisher
Nature Publishing Group
Year
2002
Tongue
English
Weight
310 KB
Volume
416
Category
Article
ISSN
0028-0836

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✍ M. Enyo 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 716 KB

A quantitative analysis is presented of the hydrogen pressure that is in equilibrium with adsorbed hydrogen at a Pd cathode and discussed on the basis of a mixed-controlled Volmer-Tafel mechanism of the hydrogen electrode reaction. Experimental evidence which supports this, but not the Volmer-Heyrov