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A Statistical Mechanical Theory of the Lindemann Time Delay in Unimolecular Reactions

✍ Scribed by Whatley, Thomas A.; Swinehart, D. F.

Book ID
126777421
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
327 KB
Volume
91
Category
Article
ISSN
0002-7863

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A New Formulation of the Lindemann Mecha
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✍ Ren-Yuan Qian πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 275 KB

## Abstract A new formulation of the Lindemann mechanism of unimolecular reactions in gaseous phase is presented, without the use of steady state hypothesis. It is hereby shown that the nature of applicability of steady state hypothesis in the regime of high reactant gas pressure is different from