✦ LIBER ✦

Observation and Analysis of theA1[formula]State of6Li2fromv= 0 to the Dissociation Limit

✍ Scribed by C. Linton; F. Martin; I. Russier; A.J. Ross; P. Crozet; S. Churassy; R. Bacis

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 324 KB
Volume: 175
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1996.0039

No coin nor oath required. For personal study only.

✦ Synopsis

Interacting rovibrational levels of the F 1 S / g and E 1 S / g states of 6 Li 2 have been excited via the optical-optical doubleresonance process, (F,

The resulting fluorescence in the region 7000-11 000 cm 01 , which has been examined at high resolution with a Fourier transform spectrometer, was found to consist of transitions to very high levels of the A 1 S / u state. These are only observed when there is an interaction between the F state level and an E state level above the shelf in the potential curve, and occur when either level is excited. Levels up to £ Å 84, Ç2.5 cm 01 below the dissociation limit, have been assigned and the data extend well into the long-range region, up to R Ç 51 A ˚. An analysis of the data in this region has yielded the following long-range parameters for the A 1 S / state: D 0 Å 9214.68(5) cm 01 , D e Å 9352.27(5) cm 01 , C 3 Å 3.580(10) 1 10 5 cm 01 rA ˚3, C 6 Å 1.0(2) 1 10 7 cm 01 rA ˚6. Based on the results of the analysis of the A 1 S / u state data, a value of D e (X 1 S / g ) Å 8517.03(05) cm 01 has been calculated for the dissociation energy of the ground state of 6 Li 2 .

📜 SIMILAR VOLUMES

The 21Σg+ state of 6Li2: Observation, an

The 21Σg+ state of 6Li2: Observation, analysis, and examination of the isotope effect

✍ F. Carrot; R. Bacis; S. Churassy; J. Ho; C. Linton; S. Mc Donald; F. Martin; J. 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 825 KB

Anomalous behaviour of the Landé factors

Anomalous behaviour of the Landé factors and the chemical shift close to the dissociation limit of the B state of molecular iodine

✍ G. Gouedard; M. Broyer; J. Vigué; J.C. Lehmann 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 382 KB

Resonances in a modulatwl light beam have been observed on five transitions in the visible band system of 12. L.andi factorsg/ and chemical shiftsgt have been mwsured for levels very close lo the dissociation limit of the B state. Since the B state of molecular iodine is a 311& the electronic magne

Analysis of spectra obtained by cold-ato

Analysis of spectra obtained by cold-atom photoassociation spectroscopy: the Rb2 1g and 0g− electronic states up to 100 Å

✍ C. Amiot 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 527 KB

From the published spectra of states of Rb, that lie within 35 cm-' of the 5 'S,,\* + 5 2P,,, dissociation limit it has been possible to derive the complete potential energy curves for the lg state (correlated to ' llE at short internuclear distance) and for the novel 0; 'pure long-range' state, pre

A shell model for cross relaxation in el

A shell model for cross relaxation in elpasolite crystals: application to the 3P0 and 1G4 states of Cs2NaY1−xPrxCl6

✍ Sergio O. Vasquez; Colin D. Flint 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 566 KB

A model for cross relaxation in high symmetry systems is developed. The positions of all acceptor ions and all multipole-multipole interactions may be included. The geometric factors are explicitly considered. A feature of the model is that it enables decay rates and the form of decay curves to be p

Potential energy curves and vibration-ro

Potential energy curves and vibration-rotation energies for the two purely long-range bound states 1u and 0g− of the alkali dimers M2 dissociating to M(ns2S12) + M(np2P32) with M = Na, K, Rb, and Cs

✍ B. Bussery; M. Aubert-Frécon 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 471 KB

Embodying sociology: Retrospect, progres

Embodying sociology: Retrospect, progress and prospects, Chris., S, & Shilling, C. (Eds.). (2007). Blackwell Publishing: UK; 169 pp. ISBN 978-1-4051-6794-9 The anorexic self: A personal, political analysis of a diagnostic discourse, Paula, S., & Saukko, P. (2008). State University of New York Press: USA; 134 pp. ISBN 978-0- 7914-7462-4 Critical bodies: Representations, identities and practices of weight and body management. Riley, S., Burns, M., Frith, H., & Wiggins, S. (Eds.). (2008). Palgrave Macmillan: UK; 206 pp. ISBN 978-0-230-51773-8 Critical feminist approaches to eating Dis/Orders. Malson, H., & Burns, M. (Eds.). (2009). Routledge: London; 280 pp. ISBN: 978-0-415-41810-2

✍ Lilliana Del Busso 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 47 KB 👁 2 views