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O2(1Σ+g) relaxation in collisions. Temperature dependence of the interaction with HBr

✍ Scribed by M. Braithwaite; E.A. Ogryzlo; J.A. Davidson; H.I. Schiff

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
393 KB
Volume
42
Category
Article
ISSN
0009-2614

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✦ Synopsis

Rate constants for the quenchrng of 02 ( r Xi) by HBr have been determined ever the temperature range 170 to 400 K and found to show only a very small rncre3se with rxsmg rempernture. These experimental values compare favorably with quenching probabilities calculated by assuming both short-range (repulsive) interactions and long-range (multipolar) mteraction induce the relaxation.

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