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O-Trimethylsilyl hemithioacetals and ketals. Reaction with organolithiums.

✍ Scribed by T.H. Chan; B.S. Ong


Book ID
104226034
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
241 KB
Volume
17
Category
Article
ISSN
0040-4039

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✦ Synopsis


0-Trimethylsilyl hemithioacetals have been obtained from the Pummerer rel-3 arrangement of a-trimethylsilyl sulfoxides . However, preparation of the hemithioacetal directly from the carbonyl compound was reported only for isolated casesl'4.


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Treatment of dichloromethyl-tris(trimethylsilyl)silane (Me 3 Si) 3 SiΒ±CHCl 2 (1), prepared by the reaction of tris(trimethylsilyl)silane with chloroform in presence of potassium tertbutoxide, with organolithium reagents (molar ratio 1 : 3) affords the bis(trimethylsilyl)methyl-disilanes Me 3 SiSiR 2