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Reaction of Dichloromethyltris(trimethylsilyl)silane with Organolithium Reagents: Synthesis of an Intramolecularly Donor-Stabilized Silene

✍ Scribed by Martin Mickoleit; Kathleen Schmohl; Rhett Kempe; Hartmut Oehme

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
156 KB
Volume
39
Category
Article
ISSN
0044-8249

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Transient Silenes as Versatile Synthons – The Reaction of Dichloromethyl-tris(trimethylsilyl)silane with Organolithium Reagents
✍ Kathleen Schmohl; Thoralf Gross; Helmut Reinke; Hartmut Oehme πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 German βš– 108 KB πŸ‘ 1 views

Treatment of dichloromethyl-tris(trimethylsilyl)silane (Me 3 Si) 3 SiΒ±CHCl 2 (1), prepared by the reaction of tris(trimethylsilyl)silane with chloroform in presence of potassium tertbutoxide, with organolithium reagents (molar ratio 1 : 3) affords the bis(trimethylsilyl)methyl-disilanes Me 3 SiSiR 2