Chemical kinetics databases for many elementary gas-phase reactions provide the recommended values of the Arrhenius parameters, the temperature range of their validity, and the temperature dependence of the uncertainty of the rate coefficient k. An analytical expression is derived that describes the
Numerical investigation of the uncertainty of Arrhenius parameters
✍ Scribed by László Varga; Botond Szabó; István Gy. Zsély; András Zempléni; Tamás Turányi
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 651 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0259-9791
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## Abstract Review: 37 refs.
The preceding paper describes the reanalysis by Kerr and Parsonage (following discussions with one of us, H.W.S.) of some of our published work. We are grateful to Dr. Kerr for communicating their conclusions to us. We agree in principle with their analysis, and the present communication is to repor
The different methods for the determination of Arrhenius parameters of the initiation step of azoisopropane AIP thermal decomposition in the presence of isobutene were investigated via computer simulation. The systematic errors in the methods were estimated.