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Nucleophilic Vinyl Substitution in the Synthesis of Heterocycles. (Review)

โœ Scribed by V.P. Litvinov; Ya.Yu. Yakunin; V.D. Dyachenko

Book ID
110362908
Publisher
Springer US
Year
2001
Tongue
English
Weight
374 KB
Volume
37
Category
Article
ISSN
0009-3122

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Direct C-lithiation of functionally substituted acrylates yields versatile intermediates for syntheses of butenolides, tetronates, a-hydroxytetronates, pyrrolenines, cyclopentenones, oxalacetates and maleic acid derivatives. A wide variety of substituents are compatible with this lithiation: alkyl,