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The importance of hyperconjugation in nucleophilic vinylic substitution

โœ Scribed by Apeloig, Yitzhak; Rappoport, Zvi


Book ID
120629668
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
546 KB
Volume
101
Category
Article
ISSN
0002-7863

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The kinetic data on the reactions of carbonylmetallates M'M(CO).L,, with polyfluorinated arenes and alkenes are reported. The behaviour of these transition metal anionic nucleophiles is compared with the reactivity of both carbanions, and non-transition metal centred anions.