## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Nucleophilic Replacement of Hydrogen in para-Substituted Nitrobenzenes by Phenylacetonitrile Carbanion
✍ Scribed by V. Yu. Orlov; Ya. V. Sokovikov; A. D. Kotov
- Book ID
- 110335701
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2002
- Tongue
- English
- Weight
- 54 KB
- Volume
- 38
- Category
- Article
- ISSN
- 1070-4280
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📜 SIMILAR VOLUMES
## Abstract Stabilized carbanions of malonates, 2‐phenylacetonitrile, or isopropyl 2‐phenylacetate add to __m__‐(trichloromethyl)nitrobenzene derivatives to form σ^H^ adducts that lose a chloride ion to give intermediate __exo__‐dichloromethylene nitrocyclohexadienes. These undergo re‐aromatization
Tertiary carbanions generated from a-substituted phenylacetonitriles in liquid ammonia add to nitrobenzenes in the para position to form the corresponding oH-adducts which are transformed, depending on the starting nitriles and the reaction conditions, to products of oxidative nucleophilic substitut