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Oxidative nucleophilic substitution of hydrogen in nitrobenzene with 2-phenylpropionitrile carbanion and potassium permanganate oxidant

✍ Scribed by M?kosza, Mieczyslaw; Stali?ski, Krzysztof; Kl?pka, Cezary


Book ID
125501204
Publisher
Royal Society of Chemistry
Year
1996
Tongue
English
Weight
192 KB
Volume
7
Category
Article
ISSN
1359-7345

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## Abstract Stabilized carbanions of malonates, 2‐phenylacetonitrile, or isopropyl 2‐phenylacetate add to __m__‐(trichloromethyl)nitrobenzene derivatives to form σ^H^ adducts that lose a chloride ion to give intermediate __exo__‐dichloromethylene nitrocyclohexadienes. These undergo re‐aromatization