Oxidative nucleophilic substitution of hydrogen in nitrobenzene with 2-phenylpropionitrile carbanion and potassium permanganate oxidant
✍ Scribed by M?kosza, Mieczyslaw; Stali?ski, Krzysztof; Kl?pka, Cezary
- Book ID
- 125501204
- Publisher
- Royal Society of Chemistry
- Year
- 1996
- Tongue
- English
- Weight
- 192 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1359-7345
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## Abstract Stabilized carbanions of malonates, 2‐phenylacetonitrile, or isopropyl 2‐phenylacetate add to __m__‐(trichloromethyl)nitrobenzene derivatives to form σ^H^ adducts that lose a chloride ion to give intermediate __exo__‐dichloromethylene nitrocyclohexadienes. These undergo re‐aromatization