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Nucleophilic Reactions of Unmodified Aldehyde Mediated by DEATMS

โœ Scribed by Hisahiro Hagiwara

Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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Nucleophilic reactions of propargyl acet
Nucleophilic reactions of propargyl acetates mediated by titanocene dichloride and magnesium
โœ Fanglong Yang; Gang Zhao; Yu Ding ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 86 KB

Reaction of Cp 2 TiCl 2 /Mg with propargyl acetates form allenyl titanium intermediates, which undergo nucleophilic addition reactions to aldehydes or ketones to give homopropargyl alcohols in high yields. Subsequent nucleophilic addition to acetonitrile and nucleophilic substitution with allyl brom