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Nucleophilic non-metal assisted trifluoromethylation and perfluoroalkylation reactions of organic substrates

✍ Scribed by Barata-Vallejo, Sebastián; Torviso, M. Rosario; Lantaño, Beatriz; Bonesi, Sergio M.; Postigo, Al


Book ID
121486755
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
194 KB
Volume
161
Category
Article
ISSN
0022-1139

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A simple procedure for nucleophilic perf
✍ Viacheslav A Petrov 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 77 KB

The mixture R f I and tetrakis(dimethylamino)ethylene is used for the nucleophilic perfluoroalkylation. The reaction of chlorotrimethylsilane and R f I/tetrakis(dimethylamino)ethylene in diglyme results in the formation of R f Si(CH 3 ) 3 isolated in 55-81% yield. The interaction of this system with