A simple procedure for nucleophilic perf
✍
Viacheslav A Petrov
📂
Article
📅
2001
🏛
Elsevier Science
🌐
French
⚖ 77 KB
The mixture R f I and tetrakis(dimethylamino)ethylene is used for the nucleophilic perfluoroalkylation. The reaction of chlorotrimethylsilane and R f I/tetrakis(dimethylamino)ethylene in diglyme results in the formation of R f Si(CH 3 ) 3 isolated in 55-81% yield. The interaction of this system with