Nucleophilic character of alkyl radicals—XIII: Absolute rate constants for the addition of alkyl radicals to acrylonitrile and methyl acrylate
✍ Scribed by Tullio Caronna; Attilio Citterio; Maurizio Ghirardini; Francesco Minisci
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 413 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants
Absolute rate constants and thzir temperature dependence were determined by time-resolved electron spin resonance for the addition of the radicals PhcH, and PhcMe, to a variety of alkenes in toluene solution. To vinyl monomers CH,=CXY, PhCH, adds at the unsubstituted C-atom with rate constants rangi