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Nucleophilic character of alkyl radicals—XIII: Absolute rate constants for the addition of alkyl radicals to acrylonitrile and methyl acrylate

✍ Scribed by Tullio Caronna; Attilio Citterio; Maurizio Ghirardini; Francesco Minisci


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
413 KB
Volume
33
Category
Article
ISSN
0040-4020

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✍ J. Q. Wu; H. Fischer 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 753 KB

Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants

Absolute Rate Constants for the Addition
✍ Manfred Walbiner; Jie Qiang Wu; Hanns Fischer 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 German ⚖ 792 KB

Absolute rate constants and thzir temperature dependence were determined by time-resolved electron spin resonance for the addition of the radicals PhcH, and PhcMe, to a variety of alkenes in toluene solution. To vinyl monomers CH,=CXY, PhCH, adds at the unsubstituted C-atom with rate constants rangi