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Nucleophilic carbenes and the wanzlick equilibrium: A reinvestigation

✍ Scribed by Michael K. Denk; Ken Hatano; Martin Ma


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
254 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis


Contrary to earlier studies, mixtures of enetetramines A=A and B=B readily exchange their carbene units upon heating (100 -175 oC) to give the cross-over olefins A=B. The absence of such exchange reactions has formerly been used as evidence against the dissociation of enetetramines into free carbenes by Lemal et al. andWinbergetal.


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