Nucleophilic carbenes and the wanzlick equilibrium: A reinvestigation
✍ Scribed by Michael K. Denk; Ken Hatano; Martin Ma
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 254 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Contrary to earlier studies, mixtures of enetetramines A=A and B=B readily exchange their carbene units upon heating (100 -175 oC) to give the cross-over olefins A=B. The absence of such exchange reactions has formerly been used as evidence against the dissociation of enetetramines into free carbenes by Lemal et al. andWinbergetal.
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