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ChemInform Abstract: The “Wanzlick Equilibrium”

✍ Scribed by Volker P. W. Boehm; Wolfgang A. Herrmann


Publisher
John Wiley and Sons
Year
2001
Weight
25 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.


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Contrary to earlier studies, mixtures of enetetramines A=A and B=B readily exchange their carbene units upon heating (100 -175 oC) to give the cross-over olefins A=B. The absence of such exchange reactions has formerly been used as evidence against the dissociation of enetetramines into free carbene