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Nucleophilic alkenes. IV. Addition of 1,1-dialkoxyethenes to 1,4-benzoquinones. The 1 : 1-process

✍ Scribed by Cameron, DW; Crossley, MJ

Book ID
120711469
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1978
Tongue
English
Weight
515 KB
Volume
31
Category
Article
ISSN
0004-9425

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afforded Diels-Alder adduct 14 and fragmentation product 32 with 2 and 3 respectively whereby reaction occurred on the less substituted double bond. No adducts were isolated upon treatment of naphthoquinone-sulfide 22 with either 2 or 3. The Diels-Alder adducts of benzoquinone-sulfoxide 9 and naphth