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Nucleophilic additions to aldehydes and ketones. 3. Reactions of ortho-substituted benzaldehydes and their polarographic oxidations

✍ Scribed by Sedon, James H.; Zuman, P.


Book ID
127293263
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
698 KB
Volume
41
Category
Article
ISSN
0022-3263

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## Abstract Three new chiral 3‐substituted BINOL Schiff bases and their reductive 3‐arylaminomethyl BINOL products have been synthesized and used for the asymmetric addition reaction of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active se