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Synthesis of 3 or 3,3′-Substituted BINOL Ligands and Their Application in the Asymmetric Addition of Diethylzinc to Aromatic Aldehydes.

✍ Scribed by Qun-Sheng Guo; Bing Liu; Yong-Na Lu; Fu-Yong Jiang; Hai-Bin Song; Jin-Shan Li

Publisher
John Wiley and Sons
Year
2006
Weight
18 KB
Volume
37
Category
Article
ISSN
0931-7597

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3-Substituted BINOL Schiff bases and the
3-Substituted BINOL Schiff bases and their reductive products for catalytic asymmetric addition of diethylzinc to aldehydes
✍ Bing Liu; Zhi-Bing Dong; Cao Fang; Hai-Bin Song; Jin-Shan Li 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB

## Abstract Three new chiral 3‐substituted BINOL Schiff bases and their reductive 3‐arylaminomethyl BINOL products have been synthesized and used for the asymmetric addition reaction of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active se