Nucleophilic Addition Reactions of Bridged Triene η6-Chromiumtricarbonyl Complexes.
✍ Scribed by Rohan E. J. Beckwith; Michael B. Gravestock; Nigel S. Simpkins
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 185 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Base hydrolysis reactions of [Cr(tmpa)(NCSe)] 2 O 2ϩ , [Cr(tmpa)(N 3 )] 2 O 2ϩ , and follow the pseudo-first-4ϩ 2ϩ [Cr (tmpa) (ϪO)(ϪPhPO )] [ Cr (tmpa) (ϪO)(ϪCO )] 2 2 4 2 2 3 order relationship (excess OH Ϫ ): For the com- obsd o b p p 3 plex, Ϫ2 Ϫ1 k (60ЊC) ϭ (1.50 Ϯ 0.03) ϫ 10 s ; ⌬H ‡ ϭ 61 Ϯ
## Arene Complexes of Transition Metals in Reactions with Nucleophilic Reagents. Part 27. Synthesis and Properties of (η 6 -Benzene) (η 5 -1ethyl-2,3,4-trimethylcyclopentadienyl) Complexes of Rhodium(III). -Two novel ethyl(trimethyl)cyclopentadienylrhodium complexes [(η 6 -C 6 H 6 )Rh (η 5 -EtMe