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Nucleophile-substrate complex in solution. Detection of chloride-organic chloride association and the potential role of the complexes in the SN2 reaction

✍ Scribed by Jun-ichi Hayami; Nobuo Tanaka; Nobuhisa Hihara; Aritsune Kaji

Book ID
104246663
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
214 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis

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✍ H. G. M. Edwards; A. R. Hoskins; A. F. Johnson; I. R. Lewis πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 667 KB

## Abstract Raman spectroscopic studies of the dissolution of polyacrylonitrile (PAN) in aqueous zinc halides are reported. The dissociation constants of aqueous PAN‐zinc chloride and PAN‐zinc bromide containing 60‐75% wt/wt and 65‐80% wt/wt zinc in aqueous polyacrylonitrile solutions, respectively