The electron transfer step of the reduction of Mn(acac)s and Co(acac)s by Fe(I1) in acetonitrile is preceded by the one-ended dissociation of an acac ligand and the formation of a binuclear bridged complex. After the electron transfer has taken place through the bridging ligand, the complex dissocia
Kinetics of the metal-exchange reaction of deuteroporphyrin and gematoporphyrin cadmium complexes with cobalt chloride in acetonitrile
โ Scribed by S. V. Zvezdina; M. B. Berezin; B. D. Berezin
- Book ID
- 110180712
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2007
- Tongue
- English
- Weight
- 276 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0036-0236
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## Abstract The __cis__โN/__trans__โN interconversion of the title compound containing glycine and (__R__)โ or (__S__)โleucine has been studied by polarimetric and spectrophotometric techniques. Equilibrium constants were determined on the basis of kinetic and thermodynamic data. It is shown that t